The non-relativistic bosonic ground state is studied for quantum N-body
systems with Coulomb interactions, modeling atoms or ions made of N "bosonic
point electrons" bound to an atomic point nucleus of Z "electron" charges,
treated in Born--Oppenheimer approximation. It is shown that the (negative)
ground state energy E(Z,N) yields the monotonically growing function (E(l N,N)
over N cubed). By adapting an argument of Hogreve, it is shown that its limit
as N to infinity for l > l* is governed by Hartree theory, with the rescaled
bosonic ground state wave function factoring into an infinite product of
identical one-body wave functions determined by the Hartree equation. The proof
resembles the construction of the thermodynamic mean-field limit of the
classical ensembles with thermodynamically unstable interactions, except that
here the ensemble is Born's, with the absolute square of the ground state wave
function as ensemble probability density function, with the Fisher information
functional in the variational principle for Born's ensemble playing the role of
the negative of the Gibbs entropy functional in the free-energy variational
principle for the classical petit-canonical configurational ensemble.Comment: Corrected version. Accepted for publication in Journal of
Mathematical Physic
