A mixture of hard-sphere particles and model emulsion droplets is studied
with a Brownian dynamics simulation. We find that the addition of nonwetting
emulsion droplets to a suspension of pure hard spheres can lead to both
gas-liquid and fluid-solid phase separations. Furthermore, we find a stable
fluid of hard-sphere clusters. The stability is due to the saturation of the
attraction that occurs when the surface of the droplets is completely covered
with colloidal particles. At larger emulsion droplet densities a percolation
transition is observed. The resulting networks of colloidal particles show
dynamical and mechanical properties typical of a colloidal gel. The results of
the model are in good qualitative agreement with recent experimental findings
[E. Koos and N. Willenbacher, Science 331, 897 (2011)] in a mixture of
colloidal particles and two immiscible fluids.Comment: 5 figures, 5 page