The green (5577 \AA) and red-doublet (6300, 6364 \AA) lines are prompt
emissions of metastable oxygen atoms in the 1S and 1D states,
respectively, that have been observed in several comets. The value of intensity
ratio of green to red-doublet (G/R ratio) of 0.1 has been used as a benchmark
to identify the parent molecule of oxygen lines as H2O. A coupled
chemistry-emission model is developed to study the production and loss
mechanisms of O(1S) and O(1D) atoms and the generation of red and green
lines in the coma of C/1996 B2 Hyakutake.
The G/R ratio depends not only on photochemistry, but also on the projected
area observed for cometary coma, which is a function of the dimension of the
slit used and geocentric distance of the comet. Calculations show that the
contribution of photodissociation of H2O to the green (red) line emission is
30 to 70% (60 to 90%), while CO2 and CO are the next potential sources
contributing 25 to 50% (<5%). The ratio of the photo-production rate of
O(1S) to O(1D) would be around 0.03 (± 0.01) if H2O is the main
source of oxygen lines, whereas it is ∼0.6 if the parent is CO2. Our
calculations suggest that the yield of O(1S) production in the
photodissociation of H2O cannot be larger than 1%. The model calculated
radial brightness profiles of the red and green lines and G/R ratios are in
good agreement with the observations made on comet Hyakutake in March 1996