We present a low-resolution (R ≡ λ/Δλ ≈ 90), 5.5-38 μm spectral sequence of a sample of M, L, and T dwarfs obtained with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope. The spectra exhibit prominent absorption bands of H_2O at 6.27 μm, CH_4 at 7.65 μm, and NH_3 at 10.5 μm and are relatively featureless at λ ≳ 15 μm. Three spectral indices that measure the strengths of these bands are presented; H_2O absorption features are present throughout the MLT sequence, while the CH_4 and NH_3 bands first appear at roughly the L/T transition. Although the spectra are, in general, qualitatively well matched by synthetic spectra that include the formation of spatially homogeneous silicate and iron condensate clouds, the spectra of the mid-type L dwarfs show an unexpected flattening from roughly 9 to 11 μm. We hypothesize that this may be a result of a population of small silicate grains that are not predicted in the cloud models. The spectrum of the peculiar T6 dwarf 2MASS J0937+2931 is suppressed from 5.5 to 7.5 μm relative to typical T6 dwarfs and may be a consequence of its mildly metal-poor/high surface gravity atmosphere. Finally, we compute bolometric luminosities of a subsample of the M, L, and T dwarfs by combining the IRS spectra with previously published 0.6-4.1 μm spectra and find good agreement with the values of Golimowski et al., who use L'- and M'-band photometry to account for the flux emitted at λ > 2.5 μm
