Under the assumption that μ is a non-doubling measure on Rd, the authors obtain the (Lp,Lq)-boundedness and the weak type endpoint estimate for the multilinear commutators generated by fractional integrals with RBMO(μ) functions of Tolsa or with OscexpLr(μ) functions for r≥1, where OscexpLr(μ) is a space of Orlicz type satisfying that OscexpLr(μ)=RBMO(μ) if r=1 and OscexpLr(μ)⊂RBMO(μ) if r>1