Heats of solution and related thermochemical properties of some rare earth metals and chlorides

Abstract

An isothermally jacketed calorimeter has been constructed to measure the changes in heat content accompanying the solution of some rare earth metals and compounds. To check the performance of the apparatus, the integral heats of solution of potassium nitrate in water at 25°C have been measured. The values corrected to infinite dilution by use of relative apparent molal heat content data in the literature give 8384 +/- 12 cals/mole. The result agrees well with the values reported by others

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