The performance of a CAEN DT5751 digitiser for nuclear safeguards and security applications is discussed. The pulse shape processing firmware embedded in the digitiser was tested with a EJ-309 liquid scintillator, exposed to gamma and neutron radiation from radioactive sources and from a Van de Graaff and cyclotron-based accelerator. Software modules were developed for data acquisition and online analysis, and for more advanced off-line processing of data acquired in list mode. The potential use of a scintillator coupled to the digitiser for the detection of both gamma-rays and neutrons has been demonstrated.JRC.D.4-Standards for Nuclear Safety, Security and Safeguard