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Theory of direct initiation of gaseous detonations and comparison with experiment

Abstract

In this work we discuss the application of an evolution equation that we have developed for the dynamics of a slowly evolving weakly-curved detonation to a problem of direct detonation initiation. Despite the relative simplicity of the theory, it successfully explains basic features of the initiation process which are observed in experiments and numerical simulations. Moreover, the theory allows one to calculate initiation energies based on the explosive chemical and thermodynamic properties only, without having to invoke significant modeling assumptions. The evolution equation exhibits the competing effects of the exothermic heat release, curvature, and shock acceleration. The detonation dynamics during the initiation depends on the relative strength of the heat release and flow divergence, resulting in successful initiation of self-sustained detonation if the heat release is sufficiently stronger than divergence or in failure if otherwise. Using global kinetic data from Caltech detonation database, which are derived from detailed chemical calculations, we have calculated critical initiation energies of spherical detonation for hydrogen-oxygen, hydrogen-air, and ethylene-air mixtures at various equivalence ratios and found a very good agreement with recent experimental data.published or submitted for publicationis peer reviewe

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