3D nanoripples, self-assembled form birefringence and ultrafast laser calligraphy in transparent materials

Abstract

Modification of transparent materials with ultrafast lasers has attracted considerable interest due to a wide range of applications including laser surgery, integrated optics, optical data storage, 3D micro- and nanostructuring [1]. Three different types of material modifications can be induced with ultrafast laser irradiation in the bulk of a transparent material, silica glass in particular: an isotropic refractive index change (type 1); a form birefringence associated with self-assembled nanogratings (3D nanoripples) and negative refractive index change (type 2) [2,3]; and a void (type 3). In fused silica the transition from type 1 to type 2 and finally to type 3 modification is observed with an increase of fluence. Recently, a remarkable phenomenon in ultrafast laser processing of transparent materials has been reported manifesting itself as a change in material modification by reversing the writing direction [4]. The phenomenon has been interpreted in terms of anisotropic plasma heating by a tilted front of the ultrashort laser pulse. Moreover a change in structural modification has been demonstrated in glass by controlling the direction of pulse front tilt, achieving a calligraphic style of laser writing which is similar in appearance to that inked with the bygone quill pen [5]. It has also been a common belief that in a homogeneous medium the photosensitivity and corresponding light-induced material modifications do not change on the reversal of light propagation direction. Moreover a new phenomenon of ultrafast light blade, representing itself the first evidence of anisotropic sensitivity of isotropic medium to femtosecond laser radiation has been recently discovered [6]. We anticipate that the observed phenomena will open new opportunities in laser material processing, laser surgery, optical manipulation and data storage