A molten Pb Bi alloy will be used as coolant in MYRRHA (Multi-purpose hybrid research reactor for high-tech applications), a prototype of an accelerator-driven nuclear fission reactor (“generation IV reactor”) that will be built at the Belgian Nuclear Research Center (start of construction in 2015, start of operation in 2025). Neutron capture by 209-Bi will inevitably lead to the appearance of 210-Po in the coolant (about 2 kg in the entire coolant volume of MYRRHA). In order to study interactions of Po with the coolant, knowledge of the Pb Bi Po phase diagram is required. Knowledge of the Pb Bi Te phase diagram is also desirable, since Po-containing systems, due to the high radiotoxicity of Po, are difficult to investigate experimentally. Therefore, analogies with the Pb Bi Te ternary system could lead indirectly to a better understanding also of the Pb Bi Po system