Despite the promise of extremely high theoretical capacity (2Li + O_2 ↔ Li_2O_2, 1675 mAh per gram of oxygen), many challenges currently impede development of Li/O_2 battery technology. Finding suitable electrode and electrolyte materials remains the most elusive challenge to date. A radical new approach is to replace volatile, unstable and air-intolerant organic electrolytes common to prior research in the field with alkali metal nitrate molten salt electrolytes and operate the battery above the liquidus temperature (>80 °C). Here we demonstrate an intermediate temperature Li/O_2 battery using a lithium anode, a molten nitrate-based electrolyte (e.g., LiNO_3–KNO_3 eutectic) and a porous carbon O_2 cathode with high energy efficiency (∼95%) and improved rate capability because the discharge product, lithium peroxide, is stable and moderately soluble in the molten salt electrolyte. The results, supported by essential state-of-the-art electrochemical and analytical techniques such as in situ pressure and gas analyses, scanning electron microscopy, rotating disk electrode voltammetry, demonstrate that Li_2O_2 electrochemically forms and decomposes upon cycling with discharge/charge overpotentials as low as 50 mV. We show that the cycle life of such batteries is limited only by carbon reactivity and by the uncontrolled precipitation of Li_2O_2, which eventually becomes electrically disconnected from the O_2 electrode
