'International Symposium on Molecular Spectroscopy'
Abstract
Ammonia (NH3) has been found ubiquitous, ite.g., in the interstellar medium, low-mass stars, Jovian planets of our solar system, and possibly in the low temperature exoplanets. Their spectroscopic line parameters are essential in the accurate interpretation of the planetary and astrophysical spectra observed with Herschel, SOFIA, ALMA, and JWST.
In our previous paperfootnote{S. Yu, et al. J. Chem. Phys. (2010) 174317/1-174317/14.}, the NH3 line positions in the far-IR region were studied for the ground state and nu2 in an unprecedented accuracy, which revealed significant deficiencies in the NH3 intensities, for instance, some weak DeltaK = 3 lines were predicted to be ~100 times stronger. Measurement of line intensity for these lines in a consistent manner is demanded because the DeltaK = 3 forbidden lines are only way other than collisions and l-doubled states to excite NH3 to K>0 levels. Recalling that NH3 transition lines in the high J and K up to 18 were detected toward the galactic center in the star forming region of Sgr B2, their accurate intensity measurements are critical in explaining the observed high K excitation, which will provide insights into radiative-transfer itvs. collision excitation mechanics of interstellar NH3.
For this, we obtained a series of spectra of 14NH3 in the 50 � 550 cm−1 using a Fourier-transform spectrometer, Bruker 125HR, and AILES beam line at Synchrotron SOLEIL, France.
Line positions, intensities, and pressure-broadened half-widths have been measured using non-linear least squares spectrum fitting algorithm. In this presentation we report and discuss preliminary results of line position and intensity measurements for the inversion transitions in the ground state, nu2, 2nu2, nu4
and for the vibration-rotation transitions of nu2, 2nu2, nu4, 2nu2−nu2, nu4−nu2 and nu4−2nu2 in this region. Comparison of the new measurements with the current databases and {it ab initio} calculations will be discussed