'International Symposium on Molecular Spectroscopy'
Abstract
Rovibrational transitions associated with tunneling states in the water bending vibration in OC-H2O complex have been recorded using a supersonic jet quantum cascade laser spectrometer at 6.2 mum. Analysis of the resulting spectra is facilitated by incorporating fits of previously recorded microwave and submillimeter data accounting for Coriolis coupling to obtain the levels of the ground vibrational state. The results were then used to confirm assignment of the vibration and explore the nature of tunneling dynamics in associated vibrationally excited states of the complex. A seven-dimension textit{ab initio} interaction potential is constructed for the complex. The available spectroscopic data is used to generated a morphed potential. Previous prediction of the D0 of the complex will be incorporated in the analysis