International audienceIndium phosphide (InP) surfaces are greatly affected by ionic bombardment. We investigate the resulting surface perturbation through the use of the complementary analytical techniques of electrochemistry and X-ray photoelectron spectroscopy (XPS). Following bombardment, modifications to the surface were identified by a reduction in the dark open circuit potential in comparison to the pristine state. Through XPS studies, it was found that the sputtered surface was enriched with a metallic-like In contribution, which oxidized upon exposure to air. Cyclic voltammetry measurements confirmed this observation, with initial cathodic features related to an oxidized metallic In-enriched layer on the InP surface. Repeated cyclic voltammetry experiments resulted in the formation of a more In-rich overlayer due to a specific oxidation/reduction phenomenon. This behavior is very similar to that obtained by cathodic decomposition on InP surfaces