Acknowledgements MB is in receipt of a PhD studentship from the Petroleum Technology Development Fund of Nigeria. LB is supported by NERC grant NE/M010953/1. C. Taylor, W. Ritchie and J. Johnston provided skilled technical support. Sulphur isotope measurements were made at SUERC. The manuscript benefitted substantially from the careful reviews of A.G. Leslie and an anonymous referee.Peer reviewedPublisher PD