Acknowledgements Funding from the DGI (Spanish Ministry of Education and Science) through Project CTQ2009-07017 is gratefully acknowledged. E.P.M.L. wishes to thank the Universidad Nacional de Co´rdoba, Argentina, for a grant within the ‘‘Programa de Movilidad Internacional de Profesores Cuarto Centenario’’.Peer reviewedPublisher PD

Cabello, Gema

Cuesta , Angel

Gutierrez, Claudio

Leiva, Ezequiel P. M.

Physical Chemistry Chemical Physics

English

The shift with increasing concentration of alkali-metal cations of the potentials of both the spike and the hump observed in the cyclic voltammograms of Pt(111) electrodes in sulfuric acid solutions is shown to obey the simple model recently developed by us to explain the effect of non-covalent interactions at the electrical double layer. The results suggest that the model, originally developed to describe the effect of alkali-metal cations on the cyclic voltammogram of cyanide-modified Pt(111) electrodes, is of general applicability and can explain quantitatively the effect of cations on the properties of the electrical double layer.Fil: Cabello, Gema. Instituto de Química Física “Rocasolano”. Madrid; ArgentinaFil: Leiva, Ezequiel Pedro M.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Gutierrez, Claudio. Instituto de Química Física “Rocasolano”. Madrid; ArgentinaFil: Cuesta, Angel. Instituto de Química Física “Rocasolano”. Madrid; Argentina. University Of Aberdeen; Reino Unid

Leiva, Ezequiel Pedro M.

Cuesta, Angel

LAReferencia - Red Federada de Repositorios Institucionales de Publicaciones Científicas Latinoamericanas

Non-covalent interactions at electrochemicalinterfaces: one model fits all?

A model based on simple thermodynamic assumptions allows us to describe and understand the effect of alkali-metal cations on very different electroadsorption processes.</p

Gema Cabello

Ezequiel P. M. Leiva

Claudio Gutiérrez

Angel Cuesta

Crossref

Non-covalent interactions at electrochemical interfaces: one model fits all?

CONICET Digital

Acknowledgements Funding from the DGI (Spanish Ministry of Education and Science) through Project CTQ2009-07017 is gratefully acknowledged. E.P.M.L. wishes to thank the Universidad Nacional de Co´rdoba, Argentina, for a grant within the ‘‘Programa de Movilidad Internacional de Profesores Cuarto Centenario’’.Peer reviewe

Aberdeen University Research

Non-covalent interactions at electrochemical interfaces : one model fits all?

https://ri.conicet.gov.ar/bitstream/11336/31349/2/CONICET_Digital_Nro.4e5f0d93-eee9-468b-9b8d-68ab47a78515_A.pdf

Non-covalent interactions at electrochemical interfaces : one model fits all?

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LAReferencia - Red Federada de Repositorios Institucionales de Publicaciones Científicas Latinoamericanas

Crossref

CONICET Digital

Aberdeen University Research