The role of β decay as a low-energy probe of physics beyond the
Standard Model is reviewed. Traditional searches for deviations from the
Standard Model structure of the weak interaction in β decay are discussed
in the light of constraints from the LHC and the neutrino mass. Limits on the
violation of time-reversal symmetry in β decay are compared to the strong
constraints from electric dipole moments. Novel searches for Lorentz symmetry
breaking in the weak interaction in β decay are also included, where we
discuss the unique sensitivity of β decay to test Lorentz invariance. We
end with a roadmap for future β-decay experiments.Comment: Accepted for publication in Rev. Mod. Phys. 86 pages, 13 figure