The linear Boltzmann equation describes the macroscopic transport of a gas of
non-interacting point particles in low-density matter. It has wide-ranging
applications, including neutron transport, radiative transfer, semiconductors
and ocean wave scattering. Recent research shows that the equation fails in
highly-correlated media, where the distribution of free path lengths is
non-exponential. We investigate this phenomenon in the case of polycrystals
whose typical grain size is comparable to the mean free path length. Our
principal result is a new generalized linear Boltzmann equation that captures
the long-range memory effects in this setting. A key feature is that the
distribution of free path lengths has an exponential decay rate, as opposed to
a power-law distribution observed in a single crystal