Accurate investigations of quantum level energies in molecular systems are
shown to provide a test ground to constrain the size of compactified extra
dimensions. This is made possible by the recent progress in precision metrology
with ultrastable lasers on energy levels in neutral molecular hydrogen (H2,
HD and D2) and the molecular hydrogen ions (H2+, HD+ and D2+).
Comparisons between experiment and quantum electrodynamics calculations for
these molecular systems can be interpreted in terms of probing large extra
dimensions, under which conditions gravity will become much stronger. Molecules
are a probe of space-time geometry at typical distances where chemical bonds
are effective, i.e. at length scales of an \AA. Constraints on compactification
radii for extra dimensions are derived within the Arkani-Hamed-Dimopoulos-Dvali
framework, while constraints for curvature or brane separation are derived
within the Randall-Sundrum framework. Based on the molecular spectroscopy of
D2 molecules and HD+ ions, the compactification size for seven extra
dimensions (in connection to M-theory defined in 11 dimensions) of equal size
is shown to be limited to R7<0.6μm. While limits on compactification
sizes of extra dimensions based on other branches of physics are compared, the
prospect of further tightening constraints from the molecular method is
discussed