The advent of high-resolution spectrographs and detailed stellar atmosphere
modelling has strengthened the need for accurate molecular data.
Carbon-enhanced metal-poor (CEMP) stars spectra are interesting objects with
which to study transitions from the CH molecule. We combine programs for
spectral analysis of molecules and stellar-radiative transfer codes to build an
extensive CH linelist, including predissociation broadening as well as newly
identified levels. We show examples of strong predissociation CH lines in CEMP
stars, and we stress the important role played by the CH features in the
Bond-Neff feature depressing the spectra of barium stars by as much as 0.2
magnitudes in the λ=3000 -- 5500 \AA\ range. Because of the extreme
thermodynamic conditions prevailing in stellar atmospheres (compared to the
laboratory), molecular transitions with high energy levels can be observed.
Stellar spectra can thus be used to constrain and improve molecular data.Comment: 33pages, 15 figures, accepted in A&A external data available at
http://www.astro.ulb.ac.be/~spectrotools