Using the Penning trap mass spectrometer TITAN, we performed the first direct
mass measurements of 20,21Mg, isotopes that are the most proton-rich members of
the A = 20 and A = 21 isospin multiplets. These measurements were possible
through the use of a unique ion-guide laser ion source, a development that
suppressed isobaric contamination by six orders of magnitude. Compared to the
latest atomic mass evaluation, we find that the mass of 21Mg is in good
agreement but that the mass of 20Mg deviates by 3{\sigma}. These measurements
reduce the uncertainties in the masses of 20,21Mg by 15 and 22 times,
respectively, resulting in a significant departure from the expected behavior
of the isobaric multiplet mass equation in both the A = 20 and A = 21
multiplets. This presents a challenge to shell model calculations using either
the isospin non-conserving USDA/B Hamiltonians or isospin non-conserving
interactions based on chiral two- and three-nucleon forces.Comment: 5 pages, 2 figure