Many-body theory is developed to calculate the γ-spectra for positron
annihilation with valence and core electrons in the noble gas atoms. A proper
inclusion of correlation effects and core annihilation provides for an accurate
description of the measured spectra [Iwata \textit{et al.}, Phys. Rev. Lett.
{\bf 79}, 39 (1997)]. The theory enables us to calculate the enhancement
factors γnl, which describe the effect of electron-positron
correlations for annihilation on individual electron orbitals nl. We find
that the enhancement factors scale with the orbital ionization energy Inl
(in electron-volt), as γnl=1+A/Inl+(B/Inl)β,
where A≈40~eV, B≈24~eV and β≈2.3.Comment: 5 pages, 5 figure