We examine the time-resolved resonance energy transfer of excitons from
single n-butyl amine-bound, chloride-terminated nanocrystals to two-dimensional
graphene through time-correlated single photon counting. The radiative
biexponential lifetime kinetics and blinking statistics of the individual
surface-modified nanocrystal elucidate the non-radiative decay channels.
Blinking modification as well as a 4 times reduction in spontaneous emission
were observed with the short chloride and n-butylamine ligands, probing the
energy transfer pathways for the development of graphene-nanocrystal
nanophotonic devices
