Most of magnetic transitions related to Ce ordering are found below
T_ord~12K. Among the few cases exceeding that temperature, two types of
behaviors can be distinguished. One of them is related to the rare cases of Ce
binary compounds formed in BCC structures, with a quartet ground state, whose
degeneracy is reduced by undergoing different types of transitions mostly
structural. The other group shows evidences of itinerant character with the
outstanding example of CeRh_3B_2 showing the highest T_ord=115K. The second
highest ordering temperature has been reported for CeScGe with T_ord=47K, but
the nature of this magnetic state has not been investigated very deeply. In
order to shed more light into this unusual high temperature ordering we studied
the structural, magnetic, transport and thermal properties of CeTi_1-xSc_xGe
alloys in the stability range of the CeScSi-type structure 0.25<x<1 This system
presents a rich variety of magnetic behaviors along this concentration range,
with the magnetic ordering growing from ferromagnetic (FM) T_C~7K up to an
antiferromagnetic (AFM) transition at T_N=47K. The different regions show the
following characteristics: i) on the Ti rich side (0.25<x<0.50) it exhibits a
FM ground state (GS) with large saturation magnetization values M_sat up to
~1.15 mu_B. ii) Around x=0.60, the first crystal electric field excited doublet
starts to contribute to the GS magnetic properties. Furthermore an AFM
component with a connected metamagnetic transition appears. iii) At x=0.65 a
clear change in the GS nature is associated to a critical point above which the
GS properties can be described like for an itinerant system (with decreasing
M_sat) and an effective GS degeneracy N_eff=4. iv) For x>0.65, the magnetic
phase boundary splits into two transitions, with an intermediate phase
presenting incommensurate spin density waves features.Comment: 8 pages, 10 figure