Context. The observation of carbon-rich disks have motivated several studies
questioning the influence of the C/O ratio on their gas phase composition in
order to establish the connection between the metallicity of hot-Jupiters and
that of their parent stars.
Aims. We to propose a method that allows the characterization of the adopted
C/O ratio in protoplanetary disks independently from the determination of the
host star composition. Titanium and vanadium chemistries are investigated
because they are strong optical absorbers and also because their oxides are
known to be sensitive to the C/O ratio in some exoplanet atmospheres.
Methods. We use a commercial package based on the Gibbs energy minimization
technique to compute the titanium and vanadium equilibrium chemistries in
protoplanetary disks for C/O ratios ranging from 0.05 to 10. Our calculations
are performed for pressures ranging from 1e-6 to 1e-2 bar, and for temperatures
ranging from 50 to 2000 K.
Results. We find that the vanadium nitride/vanadium oxide and titanium
hydride/titanium oxide gas phase ratios strongly depend on the C/O ratio in the
hot parts of disks (T > 1000 K). Our calculations suggest that, in these
regions, these ratios can be used as tracers of the C/O value in protoplanetary
disks.Comment: Accepted for publication in A&
