We call a connected Lie group endowed with a left-invariant Lorentzian flat
metric Lorentzian flat Lie group. In this Note, we determine all Lorentzian
flat Lie groups admitting a timelike left-invariant Killing vector field. We
show that these Lie groups are 2-solvable and unimodular and hence geodesically
complete. Moreover, we show that a Lorentzian flat Lie group (G,μ)
admits a timelike left-invariant Killing vector field if and only if
G admits a left-invariant Riemannian metric which has the same
Levi-Civita connection of μ. Finally, we give an useful characterization of
left-invariant pseudo-Riemannian flat metrics on Lie groups G
satisfying the property: for any couple of left invariant vector fields X and
Y their Lie bracket [X,Y] is a linear combination of X and Y