Gas-giant planets emit a large fraction of their light in the mid-infrared
(≳3μm), where photometry and spectroscopy are critical to our
understanding of the bulk properties of extrasolar planets. Of particular
importance are the L and M-band atmospheric windows (3-5μm), which are the
longest wavelengths currently accessible to ground-based, high-contrast
imagers. We present binocular LBT AO images of the HR 8799 planetary system in
six narrow-band filters from 3-4μm, and a Magellan AO image of the 2M1207
planetary system in a broader 3.3μm band. These systems encompass the five
known exoplanets with luminosities consistent with L→T transition
brown dwarfs. Our results show that the exoplanets are brighter and have
shallower spectral slopes than equivalent temperature brown dwarfs in a
wavelength range that contains the methane fundamental absorption feature
(spanned by the narrowband filters and encompassed by the broader 3.3μm
filter). For 2M1207 b, we find that thick clouds and non-equilibrium chemistry
caused by vertical mixing can explain the object's appearance. For the HR 8799
planets, we present new models that suggest the atmospheres must have patchy
clouds, along with non-equilibrium chemistry. Together, the presence of a
heterogeneous surface and vertical mixing presents a picture of dynamic
planetary atmospheres in which both horizontal and vertical motions influence
the chemical and condensate profiles.Comment: Accepted to Ap