We show that every Hankel operator H is unitarily equivalent to a
pseudo-differential operator A of a special structure acting in the space
L2(R). As an example, we consider integral operators H in the
space L2(R+) with kernels P(ln(t+s))(t+s)−1 where
P(x) is an arbitrary real polynomial of degree K. In this case, A is a
differential operator of the same order K. This allows us to study spectral
properties of Hankel operators H with such kernels. In particular, we show
that the essential spectrum of H coincides with the whole axis for K odd,
and it coincides with the positive half-axis for K even. In the latter case
we additionally find necessary and sufficient conditions for the positivity of
H. We also consider Hankel operators whose kernels have a strong singularity
at some positive point. We show that spectra of such operators consist of the
zero eigenvalue of infinite multiplicity and eigenvalues accumulating to
+∞ and −∞. We find the asymptotics of these eigenvalues