Transient Grating experiments performed on supercooled LiCl, RH2O solutions
with R>6 reveal the existence of a strong, short time, extra signal which
superposes to the normal signal observed for the R=6 solution and other glass
forming systems. This extra signal shows up below 190 K, its shape and the
associated timescale depend only on temperature, while its intensity increases
with R. We show that the origin of this signal is a phase separation between
clusters with a low solute concentration and the remaining, more concentrated,
solution. Our analysis demonstrates that these clusters have a nanometer size
and a composition which are rather temperature independent, while increasing R
simply increases the number of these clusters.Comment: 19 pages+ 8 figures+ 2 table
