The spectral line polarization of the radiation emerging from a magnetized
astrophysical plasma depends on the state of the atoms within the medium, whose
determination requires considering the interactions between the atoms and the
magnetic field, between the atoms and photons (radiative transitions), and
between the atoms and other material particles (collisional transitions). In
applications within the framework of the multiterm model atom (which accounts
for quantum interference between magnetic sublevels pertaining either to the
same J-level or to different J-levels within the same term) collisional
processes are generally neglected when solving the master equation for the
atomic density matrix. This is partly due to the lack of experimental data
and/or of approximate theoretical expressions for calculating the collisional
transfer and relaxation rates (in particular the rates for interference between
sublevels pertaining to different J-levels, and the depolarizing rates due to
elastic collisions). In this paper we formally define and investigate the
transfer and relaxation rates due to isotropic inelastic and superelastic
collisions that enter the statistical equilibrium equations of a multiterm
atom. Under the hypothesis that the atom-collider interaction can be described
by a dipolar operator, we provide expressions that relate the collisional rates
for interference between different J-levels to the usual collisional rates for
J-level populations. Finally, we apply the general equations to the case of a
two-term atom with unpolarized lower term, illustrating the impact of inelastic
and superelastic collisions on scattering polarization through radiative
transfer calculations in a slab of stellar atmospheric plasma anisotropically
illuminated by the photospheric radiation field.Comment: Accepted for publication in Astronomy & Astrophysic