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Gibbs vs. Non-Gibbs in the Equilibrium Ensemble Approach to Disordered Systems

Abstract

We describe the salient ideas of the equilibrium ensemble approach to disordered systems, paying due attention to the appearance of non-Gibbsian measures. A canonical scheme of approximations – constrained annealing – is described and characterised in terms of a Gibbs ’ variational principle for the free energy functional. It provides a family of increasing exact lower bounds of the quenched free energy of disordered systems, and is shown to avoid the use of non-Gibbsian measures. The connection between the equilibrium ensemble approach and conventional lowconcentration expansions or perturbation expansions about ordered reference systems is also explained. Finally applications of the scheme to a number of disordered Ising models and to protein folding are briefly reviewed. AMS subject classification: 82B05 Classical equilibrium statistical mechanics 82B44 Disordered systems Key words: Morita method, disordered systems, variational bounds, non-Gibbsiannes

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