The prospects are presented for precise measurements of the branching ratios of the purely leptonic Bc+→τ+ντ and B+→τ+ντ decays at the Future Circular Collider (FCC). This work is focused on the hadronic τ+→π+π+π−νˉτ decay in both Bc+→τ+ντ and B+→τ+ντ processes. Events are selected with two Boosted Decision Tree algorithms to optimise the separation between the two signal processes as well as the generic hadronic Z decay backgrounds. The range of the expected precision for both signals are evaluated in different scenarios of non-ideal background modelling. This paper demonstrates, for the first time, that the B+→τ+ντ decay can be well separated from both Bc+→τ+ντ and generic Z→bbˉ processes in the FCC-ee collision environment and proposes the corresponding branching ratio measurement as a novel way to determine the CKM matrix element ∣Vub∣. The theoretical impacts of both B+→τ+ντ and Bc+→τ+ντ measurements on New Physics cases are discussed for interpretations in the generic Two-Higgs-doublet model and leptoquark models