The permeability coefficient of coal seams is a key parameter that judges the difficulty of gas flow in coal seams. In the current calculation formula for the permeability coefficient of coal seams, the coefficient of the nonlinear partial differential equation with variable pressure is assumed to be a constant, which leads to significant errors in the theoretical derivation results and results in significant deviations in the permeability coefficient measured on site. To solve the inaccurate determination problem of the coal seam permeability coefficient, this paper derived the process of using the radial flow rate method to test the coal seam permeability coefficient, and pointed out the problems of this method during the derivation process. Based on the Langmuir's gas content and Darcy's law, a dimensionless model was established, and the model solution results were inverted and fitted. A new calculation formula for the coal seam permeability coefficient was obtained, which was verified by on-site drilling data. The current testing method for coal seam permeability coefficient was revised, and an accurate and reliable new method for calculating the coal seam permeability coefficient was proposed. The results indicate that using a parabolic equation to represent the coal seam gas content and treating variable p1.5 as a constant to derive the coal seam permeability coefficient calculation formula is equivalent to fitting the gas content into a proportional relationship with the square of pressure. There are theoretical problems and significant errors in actual calculations. Using the Langmuir dimensionless model to calculate Y' for inversion fitting can solve the shortcomings of current calculation methods. When the product of the adsorption constant b and the original gas pressure p0 (the dimensionless original gas pressure) is different, the function curve of the dimensionless gas emission velocity Y' and the dimensionless time Fo' is significantly different. Therefore, the permeability coefficient calculation formula containing the dimensionless original gas pressure was obtained. When the coal seam and drilling conditions are constant, the values of the coal seam permeability coefficient λ calculated from the gas emission volume at different times have a good reproducibility. The new on-site measurement method for the permeability coefficient of coal seams is completely the same as the current method without adding additional workload. However, the new calculating method is more accurate and reliable