First-order model for durability of Hanford waste glasses as a function of composition

Abstract

Two standard chemical durability tests, the static leach test MCC-1 and product consistency test PCT, were conducted on simulated borosilicate glasses that encompass the expected range of compositions to be produced in the Hanford Waste Vitrification Plant (HWVP). A first-order empirical model was fitted to the data from each test method. The results indicate that glass durability is increased by addition of Al{sub 2}O{sub 3}, moderately increased by addition of ZrO{sub 2} and SiO{sub 2}, and decreased by addition of Li{sub 2}O, Na{sub 2}O, B{sub 2}O{sub 3}, and MgO. Addition of Fe{sub 2}O{sub 3} and CaO produce an indifferent or reducing effect on durability according to the test method. This behavior and a statistically significant lack of fit are attributed to the effects of multiple chemical reactions occurring during glass-water interaction. Liquid-liquid immiscibility is suspected to be responsible for extremely low durability of some glasses

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