Enhanced performance of a PtCo recombination catalyst for reducing the H 2
concentration in the O 2 stream of a PEM electrolysis cell in the presence of a thin
membrane and a high differential pressure
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Abstract
High electrochemical efficiency at elevated current densities and low H 2 concentration in
O 2 can be achieved in PEM electrolysis using thin membrane and integrated
recombination catalyst. An enhanced PtCo alloy recombination catalyst was synthesized
and used at the anode of a membrane-electrode assembly (MEA). This allowed reducing
the H 2 concentration in the oxygen stream during electrolysis operation with a thin 50 µm
perfluorosulfonic acid (PFSA) Aquivion
®
membrane. Both dual-layer and composite anode
configurations (PtCo/IrRuOx) were investigated. The electrochemical performance of the
MEAs containing the recombination catalyst was better than a bare MEA while producing a
decrease of the H 2 content at the anode. This allowed extending the partial load operation
down to 5% at 55°C under a differential pressure of 20 bar. The effects of the cathodic
pressure and cell temperature (including evaluation of intermediate temperature operation
at 140 °C) on both electrochemical performance and H 2 concentration in the anode stream
were investigated. An excellent performance of 4 A cm
-2
at 1.75 V, at 140 °C, 20 bar
cathode pressure, 5.5 bar anode pressure, with 0.6 mg cm
-2
overall precious metal
catalysts content was recorded. At 140 °C, the MEA also showed a moderate H 2
concentration in O 2 of about 2.3 %, almost constant through most of the current density
range