Reduction of Ammonium Perrhenate by CO: a Convenient Method for Preparing Re2(CO)10

Abstract

International audienceDecacarbonyldirhenium(0), Re2(CO)10, was obtained in yields as high as 69% by carbonylation of ammonium perrhenate(VII) at 250-290 °C with CO at about 150 atm pressure in toluene as medium

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