The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values. The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.Solid-State Science & Research Meeting : June 28-30, Zagreb, 2023

Grbović Novaković,  Jasmina

Milošević Govedarović, Sanja

Mitrović Rajić, Anđela

Novaković, Nikola

Pantić, T.

Paskaš-Mamula, Bojana

Rmuš Mravik, Jelena

Repository of the Vinča Nuclear Institute (VinaR)

                                   Book of Abstracts   28 - 30 June 2023, Zagreb, Croatia                                                                  Solid-State Science & Research Zagreb, 28 - 30 June 2023     BOOK OF ABSTRACTS AND PROGRAMME     Edited and prepared by:  Nikola Biliškov Bahar Karadeniz Natalija Pantalon Juraj    Published by:  Ruđer Bošković Institute, Zagreb, Croatia     ISBN 978-953-7941-48-2  Published: June 2023                                 SOLID-STATE SCIENCE & RESEARCH 2023  Organizers:   Ruđer Bošković Institute   Department of Chemistry, Faculty of Science   Department of Physics, Faculty of Science  Institute of Physics   Organizing and Scientific Committee  Local Organization Board Krunoslav Užarević, Ruđer Bošković Institute, Zagreb Dijana Žilić, Ruđer Bošković Institute, Zagreb Nikola Biliškov, Ruđer Bošković Institute, Zagreb  Bahar Karadeniz, Ruđer Bošković Institute, Zagreb Ivana Brekalo, Ruđer Bošković Institute, Zagreb Danijela Bakarić, Ruđer Bošković Institute, Zagreb Natalija Pantalon Juraj, Ruđer Bošković Institute, Zagreb Mirta Rubčić, Department of Chemistry, Faculty of Science, University of Zagreb Ivica Đilović, Department of Chemistry, Faculty of Science, University of Zagreb Vladimir Stilinović, Department of Chemistry, Faculty of Science, University of Zagreb Dominik Cinčić, Department of Chemistry, Faculty of Science, University of Zagreb Željka Soldin, Department of Chemistry, Faculty of Science, University of Zagreb Damir Pajić, Department of Physics, Faculty of Science, University of Zagreb Dalibor Paar, Department of Physics, Faculty of Science, University of Zagreb Goran Zgrablić, Institute of Physics, Zagreb Nikolina Novosel, Institute of Physics, Zagreb                                   5  Young Investigators Board Valentina Martinez, Ruđer Bošković Institute, Zagreb Petra Stanić, Ruđer Bošković Institute, Zagreb Sara Marijan, Ruđer Bošković Institute, Zagreb Lidija Posavec, Dept. of Chemistry, Faculty of Science, University of Zagreb Nea Baus Topić, Dept. of Chemistry, Faculty of Science, University of Zagreb Lea Čolakić, Dept. of Chemistry, Faculty of Science, University of Zagreb Ozana Mišura, Dept. of Chemistry, Faculty of Science, University of Zagreb Mateja Pisačić, Dept. of Chemistry, Faculty of Science, University of Zagreb Jana Mužević, Dept. of Physics, Faculty of Science, University of Zagreb Nikola Miše, Dept. of Physics, Faculty of Science, University of Zagreb Mila Grgurić, Dept. of Chemistry, Faculty of Science, University of Zagreb Antonio Magnabosco, Dept. of Chemistry, Faculty of Science, University of Zagreb Filip Kučas, Dept. of Chemistry, Faculty of Science, University of Zagreb Ruđer Sušanj, Dept. of Chemistry, Faculty of Science, University of Zagreb  International Advisory Board Lars Borchard, Ruhr Universität Bochum, Germany Ljiljana Fruk, University of Cambridge, United Kingdom Mihails Arhangelskis, University of Warsaw, Poland Tomislav Friščić, University of Birmingham, United Kingdom Irina Petreska, Ss. Cyril and Methodius University, Skopje, North Macedonia Yulia Krupskaya, IFW Dresden, Germany Andraž Krajnc, National Institute of Chemistry, Ljubljana, Slovenia  Administrator Jurica Jurec, Ruđer Bošković Institute, Zagreb            6                                       7   SPONSORS  Organizers greatly appreciate the support by:                                                                           8                                                                     9    TABLE OF CONTENTS   Programme .................................................................................... 10 Keynote lectures ............................................................................ 15 Invited lectures .............................................................................. 21 Junior invited lectures .................................................................... 37 Oral presentations ......................................................................... 47 Poster presentations ...................................................................... 73 Presenting author index ............................................................... 137     10    Meeting programme:  All times are in CEST (GMT+2)  Wednesday, June 28  08:00- 08:45 Registration  08:45-09:00 Opening Ceremony                    Session 1  09:00-10:00 Selvan Demir (Keynote speaker), Michigan State University, USA New Advances in High-Performance Single-Molecule Magnets K03  10:00-10:30 Danielle Laurencin, Institute Charles Gerhardt, France Isotopic labeling: a valuable approach for studying reaction mechanisms in ball-milling I01  10:30-10:45 Stefanie Hutsch, Ruhr-University Bochum, Germany Mechanochemistry as Tool for Porous Organic Polymer Synthesis O1  10:45-11:00 Nikola Biliškov, Ruđer Bošković Institute, Croatia Mechanochemical preparation of Ruddlesden-Popper type perovskites O2 Coffee break                  Session 2   11:30 - 12:00 Vlado Lazarov, University of York, UK Correlation between disorder and defects in half metals and topological insulators and their functional properties I02  12:00- 12:15 Željana Bonačić Lošić, Faculty of Science, University of Split Plasmon in topological nodal line semimetal O3  12:15- 12:30 Priyanka Reddy, Department of Physics, Faculty of Science, University of Zagreb Novel electronic materials on the verge of metallicity and ionicity O5  12:30- 12:45 Matija Čulo, Institute of Physics, Zagreb Quantum vortex liquid in iron-based superconductors FeSe1-xSx and FeSe1-xTex O6                                  11   Lunch break                Session 3 14:00- 14:30 Antonio Šiber, Institute of Physics, Zagreb Mechanical design and infolding of pollen grains I03  14:30-14:45 Monika Kovačević, Faculty of Food Technology and Biotechnology, University of Zagreb Overview of ferrocene peptidomimetics – conformational analysis, DFT study and solid state JI1 14:45-15:00 Ivor Lončarić, Ruđer Bošković Institute, Croatia Thermomechanical Properties of Molecular Crystals from Machine Learning Potentials O7 15:00- 15:30 Luka Pavić, Ruđer Bošković Institute, Zagreb Investigation of Oxide Glass-(Ceramics) Employing Impedance Spectroscopy I09   15:30- 15:45 Luca Grisanti, Materials Foundry Institute (IOM) at National Research Council, Trieste, Italy Base-pairing of uracil and 2,6-diaminopurine: from cocrystals to photoreactivity   O8   15:45- 16:00 Laura Nuić, Department of Chemistry, Faculty of Science, University of Zagreb Polymerization of aromatic C-nitroso derivatives on Au(111) surface: ellipsometry, AFM and nano-FTIR study O9 Coffee break – AlphaChrom presentation               Session 4 16:30-16:45 Ivana Ban, Faculty of Science, University of Zagreb Macro-karyotype model for tumor evolution  JI2 16:45-17:00  Jasna Alić, Ruđer Bošković Institute, Croatia  Direct in situ measurement of polymorphic transition temperatures in thermo-mechanochemical reactions  JI3 17:00-17:15 Miriam Velasquez Hernandez, Graz University of Technology, Austria Resist-free micropatterning of oriented MOF films with anisotropic optical properties   JI4 17:15-17:30 Simon Renner, Graz University of Technology, Austria Extending the scope of protein encapsulation into ZIFs O10 17:30-17:45 Davide Benedetto Tiz, National Institute of Chemistry, Ljubljana, Slovenia  Lignin-based covalent adaptable networks (CANs): a possible replacement for fossil-based thermosets  O11  17:45-18:00 Aleksandra Pacanowska, Institute of Nuclear Physics Polish Academy of Sciences, Poland From thin film deposition to composite materials of switchable coordination compound  O12 18:00-20:00 Poster session (P01-P30)    12  All times are in CEST (GMT+2)  Thursday, June 29 08:00-09:00 Registration                Session 5   09:00 - 10:00 Alessandro Stroppa (Keynote speaker), Consiglio Nazionale delle Ricerche, Institute for Superconducting and Innovative Materials and Devices, (CNR-SPIN), Italy Can we generate and transfer chirality? K02  10:00 - 10:30 Denys Makarov, Helmholtz-Zentrum Dresden-Rossendorf, Germany Designing chiral magnetic responses by tailoring geometry of thin films: curvilinear ferro- and antiferromagnets I05  10:30-10:45 Krešimir Molčanov, Ruđer Bošković Institute, Croatia π-hole interactions: a new playground for materials science O13  10:45-11:00 Sharmarke Mohamed, Khalifa University of Science and Technology, UAE On the crystal engineering of mechanically responsive crystals using facet-dependent DFT Young’s moduli O14 Coffee break               Session 6   11:30 - 11:45 Nea Baus Topić, Faculty of Science, Department of Chemistry, University of Zagreb Cocrystals with copper(II) complexes as halogen bond donors JI5   11:45 - 12:00 Katarina Lisac, Ruđer Bošković Institute, Croatia Monometallic and bimetallic MOF-74 materials based on structural isomers as linkers JI6   12:00 - 12:15 Mihails Arhangelskis, University of Warsaw, Poland Ab initio prediction of structures, functional properties and solid-state reactivity of crystalline materials O15   12:15-12:30 Mateja Pisačić, Faculty of Science, Department of Chemistry, University of Zagreb Dancing crystals - mechanically and thermally stimulated crystal movements O16  12:30-12:45 Nick Vukotić, University of Windsor, Canada Therapeutic Coordination Polymers (TCPs) as Controllable Drug Release Materials O17  12:45-13:00 Francesco Carraro, Graz University of Technology, Austria  Hydrogen-bonded organic frameworks and enzymes: a new class of biocomposites O18   Lunch break                                    13                   Session 7  14:00- 14:30 Marija Milanović, University of Novi Sad, Serbia  Epitaxial La1-xSrxMnO3 thin films obtained by PAD – influence of temperature and Sr concentration  I06  14:30-15:00 Martina Lihter, Institute of Physics, Zagreb Nanofabrication, Functionalization and Applications of Atomically Thin 2D Materials I07  15:00- 15:15 Wojciech Sas, Institute of Physics, Zagreb Various strategies of synthesizing Prussian blue analogs of mixed composition into reduced dimensionality systems O19  15:15- 15:30 Igor Milanović, Vinča Institute of Nuclear Sciences, Serbia (Bi)metallic amidoboranes – synthesis, characterisation and perspective O20  15:30-15:45 Wojciech Wegner, University of Warsaw, Poland Versatile usage of the complex hydride materials O21  15:45-16:00 Matic Lozinšek, Jožef Stefan Institute, Slovenia Alkali-Metal Fluoridooxidovanadates(V) O22 Coffee break – Jasika presentation                  Session 8  16:30-17:00 Jonathan De Roo, University of Basel, Switzerland Pair Distribution Function analysis of metal oxide nanocrystals and metal oxo clusters I08  17:00- 17:30 Davor Ljubas, Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb Creation of magnetic photocatalysts for degradation of water pollutants I04  17:30-17:45 Mercedes Linares-Moreau, Graz University of Technology, Austria Fabrication of 3D-oriented MOF films and patterns from oriented ceramic nanostructures O23  17:45-18:00 Photo session (Main entrance)   18:00-20:00 Poster session (P31-P63)        14   All times are in CEST (GMT+2)  Friday, June 30  09:00-13:00 Zagreb City Tour-Lunch break            Session 9 13:00- 14:00 James Mack (Keynote speaker), University of Cincinnati, USA Mechanochemistry is just chemistry K01 14:00- 14:30 Alexey Popov, Leibniz IFW Dresden, Germany Molecular magnets with single-electron bond between rare-earth metals I10 14:30-14:45 Ana Najev, University of Zagreb, Croatia Probing the electronic properties of titanates with NMR and ESR JI7 14:45-15:00 Jedrzej Kobylarczyk, Institute of Nuclear Physics Polish Academy of Sciences, Poland Site Selective Spin Crossover in Large Undecanuclear Cyanido-Bridged Clusters O24 Coffee break            Session 10 15:30- 16:00 Andrej Zorko, Jožef Stefan Institute and Faculty of Mathematics and Physics, University of Ljubljana, Slovenia Spin liquids on the triangular spin lattice I11 16:00- 16:30 Mirela Dragomir, Jožef Stefan Institute, Slovenia Synthesis, crystal growth, and characterisation of frustrated magnets and other quantum materials I12 16:30- 17:00 Ivica Živković, EPFL, Switzerland  Entropy chase in 5d1 double perovskites I13 17:00-17:15 Pavla Šenjug, Faculty of Science, Department of Physics, University of Zagreb Magnetism and magnetic order in layered hybrid organic-inorganic tetrahalocuprate perovskites JI8 Closing ceremony and awards           ________________Solid-State Science & Research Meeting, 28-30 June 2023, Zagreb 117  P43 - Pyrophyllite modified carbon-based electrode  J. Grboivić Novaković A. Mitrović Rajić ,T. Pantić  S.Milošević Govedarović, N.Novaković,  J.Rmuš Mravik B.Paskaš Mamula 1Centre of Excellence for Hydrogen and Renewable Energy, Vinča Institute of Nuclear Sciences, National Institute of Republic of Serbia, University of Belgrade, Belgrade, POB 522, Serbia e-mail:  jasnag@vinca.rs  The main goal is to develop electrode material for the detection of traces of pesticides in food and water in a wide range of pH values.  The leading idea is to use natural clay pyrophyllite to modify carbon paste electrode. SPEX Mixer/Mill 5100 is used for mechanochemical modification. The changes in the structure of pyrophyllite before and after the grinding process were studied by means of PSD, XRD, FTIR, and DTA-TG [1]. The electrochemical behavior of the sensor was followed using differential pulse stripping voltammetry (DPSV). It is shown that obtained material can be used as electrodes in electrochemical sensors for pesticide detection in a wide range of pH.     Figure 1 DPSV in Britton – Robinson buffer at pH 8    [1] A. Mitrović Rajić, T. Pantić, S. Milošević Govedarović, B. Paskaš Mamula, N. Filipović, J. Grbović Novaković, S. Dimitrijević, Sci.  Sinter.  DOI: 10.2298/SOS220715018M, (2023)   

Pyrophyllite modified carbon-based electrode

http://vinar.vin.bg.ac.rs/bitstream/id/35143/BookAbstracts_2023.pdf

Pyrophyllite modified carbon-based electrode

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