Beware of CaBER: filament thinning rheometry doesn't give `the' relaxation time of polymer solutions

Abstract

The viscoelastic relaxation time {\tau} of a polymer solution is often measured using Capillary Breakup Extensional Rheometry (CaBER) where a droplet is placed between two plates which are pulled apart to form a thinning filament. For a slow plate retraction protocol, required to avoid inertio-capillary oscillations for low-viscosity liquids, we show experimentally that the CaBER relaxation time inferred from the exponential thinning regime is in fact an apparent relaxation time that increases significantly when increasing the plate diameter and the droplet volume. Similar results are obtained with a Dripping-onto-Substrate (DoS) method. This dependence on the flow history before the formation of the viscoelastic filament is in contradiction with polymer models such as Oldroyd-B that predict a filament thinning rate 1/3{\tau} which is a material property independent of geometrical factors. We show that this is not due to artefacts such as solvent evaporation or polymer degradation and that it cannot be universally explained by the finite extensibility of polymer chains.Comment: 18 pages, 6 figures, presented at the ICR 2023 in Athen