Two imidazolium monomeric surfactants, that is, 1-tetradecyl-1H-imidazole [14IM] and 1-hexadecyl-1H-imidazole [16IM] has been synthesized and characterized by 1H NMR,13C NMR, FTIR, HRMS spectroscopies and thermogravimetric analysis (TGA) for number and types of protons and carbon, functional groups, estimation of molecular weight and thermal stability of these compounds. The conductivity was measured in double distilled water at four different temperatures, 288, 293, 298, and 303 K. The results showed that these surfactants behave as weak electrolytes. The density and viscosity data have shown the existence of strong interactions between imidazolium surfactants and solvent (water) molecules. The results obtained from Root’s equation indicate that surfactant–solvent interactions are important than surfactant–surfactant interactions in dilute solutions, that is, below critical micellar concentration. The values of constants obtained from Einstein and Moulik equations have revealed that there was stronger and significant interaction between imidazolium surfactants and water molecules below critical micellar region. The surface tension parameters have indicated that these surfactants are good contenders to lower the surface tension of air/water interface. The results obtained from surface tension data have shown that standard change in free energy of micellization (ΔG°mic) and adsorption (ΔG°ads) were negative, indicating that these surfactants molecules have spontaneous tendencies to form micelles in solution at higher concentration and to get adsorb at the air/water interface at lower concentration. The TGA has indicated good thermally stability and activation energy for thermal decomposition was found in the range of 37.26.26–98.20.20 kJ/mol.</p