Spin-based applications of the negatively charged nitrogen-vacancy (NV)
center in diamonds require efficient spin readout. One approach is the
spin-to-charge conversion (SCC), relying on mapping the spin states onto the
neutral (NV0) and negative (NV−) charge states followed by a subsequent
charge readout. With high charge-state stability, SCC enables extended
measurement times, increasing precision and minimizing noise in the readout
compared to the commonly used fluorescence detection. Nano-scale sensing
applications, however, require shallow NV centers within a few \si{\nano
\meter} distance from the surface where surface related effects might degrade
the NV charge state. In this article, we investigate the charge state
initialization and stability of single NV centers implanted \approx
\SI{5}{\nano \meter} below the surface of a flat diamond plate. We demonstrate
the SCC protocol on four shallow NV centers suitable for nano-scale sensing,
obtaining a reduced readout noise of 5--6 times the spin-projection noise
limit. We investigate the general applicability of SCC for shallow NV centers
and observe a correlation between NV charge-state stability and readout noise.
Coating the diamond with glycerol improves both charge initialization and
stability. Our results reveal the influence of the surface-related charge
environment on the NV charge properties and motivate further investigations to
functionalize the diamond surface with glycerol or other materials for
charge-state stabilization and efficient spin-state readout of shallow NV
centers suitable for nano-scale sensing.Comment: 9 pages, 5 figure