Conductances, transference numbers, and activity coefficients of some low atomic number rare earths in aqueous solution

Abstract

The conductances, transference numbers, and activity coefficients of aqueous solutions of the chlorides of lanthanum, cerium, praseodymium, and neodymium have been determined for concentrations up to 0.1 normal . The transference numbers were determined by the moving-boundary method as developed by Longsworth and MacInnes; the activity coefficients were measured by using concentration cells with transference; and the conductances were obtained with a conventional apparatus of the type recommended by Jones and Josephs. The accuracy of all measurements was within 0.1 per cent.</p

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