In this paper we construct solutions to Ricci–DeTurck flow in four dimensions on closed manifolds which are instantaneously smooth but whose initial values g are (possibly) non-smooth Riemannian metrics whose components in smooth coordinates belong to W2,2 and satisfy a1h≤g≤aha1h≤g≤ah for some 1<a<∞ and some smooth Riemann\-ian metric h on M. A Ricci flow related solution is constructed whose initial value is isometric in a weak sense to the initial value of the Ricci–DeTurck solution. Results for a related non-compact setting are also presented. Various Lp-estimates for Ricci flow, which we require for some of the main results, are also derived. As an application we present a possible definition of scalar curvature ≥k≥k for W2,2-metrics g on closed four manifolds which are bounded in the L∞-sense by a1h≤g≤ah for some 1<a<∞ and some smooth Riemannian metric h on M