Star formation activity in molecular clouds is often found to be correlated
with the amount of material above a column density threshold of ∼1022cm−2. Attempts to connect this column density threshold to a volume density above which star formation can occur are limited by the fact
that the volume density of gas is difficult to reliably measure from
observations. We post-process hydrodynamical simulations of molecular clouds
with a time-dependent chemical network, and investigate the connection between
commonly-observed molecular species and star formation activity. We find that
many molecules widely assumed to specifically trace the dense, star-forming
component of molecular clouds (e.g. HCN, HCO+, CS) actually also exist in
substantial quantities in material only transiently enhanced in density, which
will eventually return to a more diffuse state without forming any stars. By
contrast, N2H+ only exists in detectable quantities above a volume
density of 104cm−3, the point at which CO, which reacts
destructively with N2H+, begins to deplete out of the gas phase onto
grain surfaces. This density threshold for detectable quantities of N2H+
corresponds very closely to the volume density at which gas becomes
irreversibly gravitationally bound in the simulations: the material traced by
N2H+ never reverts to lower densities, and quiescent regions of molecular
clouds with visible N2H+ emission are destined to eventually form stars.
The N2H+ line intensity is likely to directly correlate with the star
formation rate averaged over timescales of around a Myr.Comment: 10 pages, 10 figures. MNRAS accepte