Theory, using Low Energy QCD, calculated with high precision the ππ and πK scattering length. Lifetime of π+π− atoms are related with a difference of pion-pion s-wave scattering lengths with isospin 0 and 2: ∣a0−a2∣. Energy splitting between p-states (long-lived atoms) and s-states of π+π− atoms allows to investigate another combination: 2a0+a2. Lifetime of πK atoms gives information about difference of pion-kaon s-wave scattering lengths with isospin 1/2 and 3/2: ∣a1/2−a3/2∣. Experimental measurements of pion-kaon lifetimes and observation of long-lived π+π− atoms at experiment DIRAC are presente