Abstract Presented are experimental results for the difference in pair production probability (the asymmetry) for 5–150 GeV photons polarized parallel and perpendicular to a (110) plane in a 1.5 mm thick diamond 〈100〉 crystal. The photons are produced by interaction of 150 GeV electrons with an aligned diamond 〈100〉 crystal of 0.5 mm thickness. A significant asymmetry is found over the whole energy range, which corresponds to a high degree of linear polarization of the photons as well as a difference in the refractive index. This proof-of-principle result gives the possibility of producing high energy photons with circular polarization by use of a crystal. This might open for several opportunities in high energy physics like for instance the investigation of the contribution of the gluons to the spin of the nucleon