The 89Y(α, 2nγ)91Nb reaction was used to populate excited states in 91Nb. The rotation of the angular distribution of the 357 keV gamma-transition from the 21/2+ state was measured in an external magnetic field. The IPAD method was used. By applying τ =(1.33± 0.14) ns for the lifetime of the 21/2+ state at 3467 keV, the value of the g-factor 1.18 ± 0.18 was derived