Hummelen, J.C.

Meijer, E.W.

Wynberg, H.

English

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 A process for preparing substituted polycyclo-alkylidenepolycyclo-alkanes as well as said substituted polycyclo-alkylidene polycyclo-alkanesCitation for published version (APA):Hummelen, J. C., Meijer, E. W., & Wynberg, H. (1984). A process for preparing substituted polycyclo-alkylidenepolycyclo-alkanes as well as said substituted polycyclo-alkylidene polycyclo-alkanes.Document status and date:Published: 01/01/1984Document Version:Publisher’s PDF, also known as Version of Record (includes final page, issue and volume numbers)Please check the document version of this publication:• A submitted manuscript is the version of the article upon submission and before peer-review. There can beimportant differences between the submitted version and the official published version of record. Peopleinterested in the research are advised to contact the author for the final version of the publication, or visit theDOI to the publisher's website.• The final author version and the galley proof are versions of the publication after peer review.• The final published version features the final layout of the paper including the volume, issue and pagenumbers.Link to publicationGeneral rightsCopyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright ownersand it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights.            • Users may download and print one copy of any publication from the public portal for the purpose of private study or research.            • You may not further distribute the material or use it for any profit-making activity or commercial gain            • You may freely distribute the URL identifying the publication in the public portal.If the publication is distributed under the terms of Article 25fa of the Dutch Copyright Act, indicated by the “Taverne” license above, pleasefollow below link for the End User Agreement:www.tue.nl/taverneTake down policyIf you believe that this document breaches copyright please contact us at:openaccess@tue.nlproviding details and we will investigate your claim.Download date: 04. Oct. 2023EP0106863B1Publication Title:Polycycloalkylidene-polycycloalkanes, epidioxy derivatives thereof and method ofpreparation Abstract:PCT No. PCT/NL83/00014 Sec. 371 Date Dec. 7, 1983 Sec. 102(e) Date Dec. 7,1983 PCT Filed Apr. 7, 1983 PCT Pub. No. WO83/03604 PCT Pub. Date Oct.27, 1983.The invention relates to a process for preparing substitutedpolycyclo-alkylidene polycyclo-alkanes, such as substituted adamantylideneadamantanes, and the corresponding epidioxy compounds, in whichpolycyclo-alkylidene polycyclo-alkanes are halogenated with anN-halosuccinimide, tert.-butylhypohalite or sodium hypohalite/CH3COOH, thehalogenation product is optionally subjected to a substitution reaction, and thesubstituted polycycloalkylidene polycyclo-alkanes are converted to thecorresponding epidioxy compounds in a way known per se. Further, the inventionrelates to compounds of formula 44  in which A and B represent alkyleneradicals, which alkylene radicals may be attached to each other via an alkyleneradical C, and R1 represents a substituent, which, in case of4-eq.-R1-2,2'-adamantylidene adamantane cannot be chloro, hydroxy, oxo, D ora group of formula 1:  as well as to compounds of formula 45:  in which A, B andC are as defined above, and R2 is a substituent which, in case of4-eq.-R2-2,2'-epidioxy-2,2'-adamantyl adamantane cannot be chloro or hydroxy.Compounds of formula 45 are useful as thermochemiluminescent labels andprobes in the study of biological processes and in immuno-assays.------------Data supplied from the esp@cenet database - http://ep.espacenet.comThis Patent PDF Generated by Patent Fetcher(TM), a service of Stroke of Color, Inc.Patent provided by Sughrue Mion, PLLC - http://www.sughrue.com  Patent provided by Sughrue Mion, PLLC - http://www.sughrue.com  Patent provided by Sughrue Mion, PLLC - http://www.sughrue.com  

A process for preparing substituted polycyclo-alkylidene polycyclo-alkanes as well as said substituted polycyclo-alkylidene polycyclo-alkanes

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A process for preparing substituted polycyclo-alkylidene polycyclo-alkanes as well as said substituted polycyclo-alkylidene polycyclo-alkanes

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