Electrochemical sensors for detection of bisphenols

Abstract

The endocrine-disrupting chemicals (EDCs) are chemicals of very high concern that have hazards with serious consequences on human health. It influences on development of metabolic disorders, reproduction and respiratory problems. They can be found in our everyday life, from food, and personal care products to medical devices, dental products, special lenses and baby drink cans. Among several EDCs, banned Bisphenol A (BPA) and his substitute Bisphenol S (BPS) have attracted attention due to high usage during the manufacturing process for water and food packaging, in the production of epoxy resins, lacquer coating and can even be found in receipt. Due to that, there is a need for the fast, reliable and commercial detection of Bisphenols in everyday life. The gold standard for the detection of Bisphenols is chromatography and enzyme-linked immunosorbent assay, expensive and robust methods. Electrochemical sensors are a new approach to the detection of EDCs in very small quantities in complex environments. The aim of this research was to study commercial screen-printed electrodes (SPEs) as receptor elements in electrochemical sensors for the detection of BPA and BPS. Scanning electron microscopic (SEM) and Fourier transform infrared spectroscopy (FT-IR) were employed for examining the surface of the SPEs working electrodes. SPE electrodes showed very good voltammetric responses toward BPA and BPS oxidation with linear ranges between 0.5 and 50.0 μM and lower limits of detection of 0.15 μM and 0.37 μM, respectively

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