In recent years, high-resolution additive manufacturing has enabled a diverse range of low-cost methods for ultrasonic wave-front shaping. Acoustic holograms, in particular, allow for the generation of arbitrary diffraction-limited acoustic fields at megahertz frequencies from single-element transducers. These are phase plates that function as direct acoustic analogs to thin optical holograms. In this work, it is shown that, by using multiple polymer three-dimensional (3D) printing, two-material (binary) acoustic analogs to "thick"or volume optical holograms can also be generated. First, an analytic approach for designing a volume hologram that diffracts a set of input fields onto a desired set of output fields is briefly summarized. Next, a greedy-optimization approach based on random downhill binary search able to account for the constraints imposed by the chosen fabrication method is introduced. Finally, an experimental test case designed to diffract the field generated by a 2.54-cm planar lead zirconate titanate (PZT) transducer onto eight distinct patterns dependent on the direction of the incident field is used to validate the approach and the design method. Field scans of the eight target fields demonstrate that acoustic analogs of optical volume holograms can be generated using multipolymer printing and that these allow the multiplexing of distinct fields onto different incident field directions