The human brain has evolved to be very adept at recognising imperfections in human skin. In particular, observing someone’s facial skin appearance is important in recognising when someone is ill, or when finding a suitable mate. It is therefore a key goal of computer graphics research to produce highly realistic renderings of skin. However, the optical processes that give rise to skin appearance are complex and subtle. To address this, computer graphics research has incorporated more and more sophisticated models of skin reflectance. These models are generally based on static concentrations of skin chromophores; melanin and haemoglobin. However, haemoglobin concentrations are far from static, as blood flow is directly caused by both changes in facial expression and emotional state. In this thesis, we explore how blood flow changes as a consequence of changing facial expression with the aim of producing more accurate models of skin appearance. To build an accurate model of blood flow, we base it on real-world measurements of blood concentrations over time. We describe, in detail, the steps required to obtain blood concentrations from photographs of a subject. These steps are then used to measure blood concentration maps for a series of expressions that define a wide gamut of human expression. From this, we define a blending algorithm that allows us to interpolate these maps to generate concentrations for other expressions. This technique, however, requires specialist equipment to capture the maps in the first place. We try to rectify this problem by investigating a direct link between changes in facial geometry and haemoglobin concentrations. This requires building a unique capture device that captures both simultaneously. Our analysis hints a direct linear connection between the two, paving the way for further investigatio
